全文获取类型
收费全文 | 30457篇 |
免费 | 5971篇 |
国内免费 | 7770篇 |
专业分类
化学 | 23365篇 |
晶体学 | 983篇 |
力学 | 1825篇 |
综合类 | 958篇 |
数学 | 3822篇 |
物理学 | 13245篇 |
出版年
2024年 | 23篇 |
2023年 | 379篇 |
2022年 | 722篇 |
2021年 | 879篇 |
2020年 | 1042篇 |
2019年 | 1184篇 |
2018年 | 1011篇 |
2017年 | 1191篇 |
2016年 | 1254篇 |
2015年 | 1519篇 |
2014年 | 1763篇 |
2013年 | 2384篇 |
2012年 | 2723篇 |
2011年 | 2843篇 |
2010年 | 2440篇 |
2009年 | 2515篇 |
2008年 | 2792篇 |
2007年 | 2480篇 |
2006年 | 2372篇 |
2005年 | 2104篇 |
2004年 | 1690篇 |
2003年 | 1295篇 |
2002年 | 1403篇 |
2001年 | 1234篇 |
2000年 | 1133篇 |
1999年 | 792篇 |
1998年 | 453篇 |
1997年 | 315篇 |
1996年 | 293篇 |
1995年 | 265篇 |
1994年 | 280篇 |
1993年 | 248篇 |
1992年 | 181篇 |
1991年 | 159篇 |
1990年 | 127篇 |
1989年 | 113篇 |
1988年 | 103篇 |
1987年 | 73篇 |
1986年 | 69篇 |
1985年 | 67篇 |
1984年 | 56篇 |
1983年 | 47篇 |
1982年 | 36篇 |
1981年 | 37篇 |
1980年 | 17篇 |
1979年 | 30篇 |
1978年 | 9篇 |
1977年 | 8篇 |
1959年 | 8篇 |
1936年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
81.
Jong Chan Lee Jin Young Park So Young Yoon Yong Hun Bae Seung Jun Lee 《Tetrahedron letters》2004,45(1):191-193
A novel and direct method for the synthesis of α-halocarbonyl compounds using sequential treatment of carbonyl compounds with [hydroxy(tosyloxy)iodo]benzene followed by magnesium halides under solvent-free microwave irradiation conditions is described. 相似文献
82.
The authors study the singular integrals under the Hormander condition and the measure not satisfying the doubling condition. At first, if the corresponding singular integral is bounded from L2 to itself, it is proved that the maximal singular integral is bounded from L∞to RBMO except that it is infinite μ-a.e. on Rd. A sufficient condition and a necessary condition such that the maximal singular integral is bounded from L2 to itself are also obtained. There is a small gap between the two conditions. 相似文献
83.
The Iyengar Type Inequalities with Exact Estimations and the Chebyshev Central Algorithms of Integrals 总被引:3,自引:0,他引:3
Xing Hua WANG Shi Jun YANG 《数学学报(英文版)》2005,21(6):1361-1376
In this paper, both low order and high order extensions of the Iyengar type inequality are obtained. Such extensions are the best possible in the same sense as that of the Iyengar inequality. hzrthermore, the Chebyshev central algorithms of integrals for some function classes and some related problems are also considered and investigated. 相似文献
84.
ZENG Hao BAI Xingyu RAO Jun 《核工业西南物理研究院年报(英文版)》2004,(1):65-67
When we carry out lower hybrid wave heating and current driving plasma experiment at tokamak, we need mega-watt order of microwave power. The microwave signal at frequency of 2450 MHz is generated by a microwave exciter. According to the experiment's demands, the microwave exciter must provide output power of 1.5~ 2. 5 W with stabilized frequency and amplitude tobe used as the klystron input. Being amplified by the klystron, the microwave signal is transmitted through the transmitting system to the antenna and is emitted into the HL-2A tokamak. So we can see that the microwave exciter's function is very important to the lower hybrid wave heating and current driving plasma experiment. 相似文献
85.
In the ever fusion experiments in SWIP, pellet forming process was carried out through adjusting relative devices by staff member in site, which will make every pellet-forming process slight distinction and will result in pellet difference in shape, size and intensity. In the intervals of HL-2A discharges, staff member have to go site to accomplish the pellet-forming process, this wastes human power and increase the potential danger. So it is necessary to develop a remote control system to perform the pellet-forming process. The control system needs have the features of real-time, reliability and be easy to operate and maintain. 相似文献
86.
ZHU Yabin ZHOU Yueliang LIU Zhen WANG Shufang CHEN Zhenghao U Huibin YANG Guozhen XlAO Ling Ren Hongtao JIAO Yulei Zheng Minghui 《中国科学G辑(英文版)》2004,47(2):165-172
The irreversibility field (Hirr) of Y-based superconductor is much higher than that of Bi-based superconductor. Y-based superconductor is capable of maintaining stable electrical currents in high magnetic field and electric field, so it is a better suited mate-rial for electric-current applications. Commonly, the Y-based tapes comprise a YBCO thick film deposited on a flexible substrate, typically with an intermediate buffer layer, and an overcoat of noble metal. In this process, the interm… 相似文献
87.
A G 4.0 dendrimer-like poly (amido amine) (PAMAM) based on silica nanoparticles was fabricated via a divergent approach.It was built from γ-aminopropyi silica nanoparfides (APSN) core via repetitive addition of acrylate (MA) and hexylenediamine (HDA). FT-IR and EA were used to monitor the progress of dendrimer during each step. The amino group content of the resulting product increased from 0.49 to 3.72 mmol/g after the 4th generation. In addition, the percentage of grafting increased with increasing generation and reached to 65.9% after 4th generation. It was found that the resulting silica nanoparticles could be dispersed in methanol with a mean hydrodynamic particle diameter of 152.7 nm although the silica nanoparticles had agglomerated during the storage period. 相似文献
88.
Substructuring preconditioners for saddle-point problems arising from Maxwell's equations in three dimensions 总被引:1,自引:0,他引:1
This paper is concerned with the saddle-point problems arising from edge element discretizations of Maxwell's equations in a general three dimensional nonconvex polyhedral domain. A new augmented technique is first introduced to transform the problems into equivalent augmented saddle-point systems so that they can be solved by some existing preconditioned iterative methods. Then some substructuring preconditioners are proposed, with very simple coarse solvers, for the augmented saddle-point systems. With the preconditioners, the condition numbers of the preconditioned systems are nearly optimal; namely, they grow only as the logarithm of the ratio between the subdomain diameter and the finite element mesh size.
89.
A Promising MoO_x-based Catalyst for n-Heptane Isomerization 总被引:1,自引:0,他引:1
Song Hai CHAI Xin Ping WANG* Ying Jun WANG Tian Xi CAI State Key Laboratory of Fine Chemicals Dalian University of Technology Dalian 《中国化学快报》2003,14(7)
The increasing demand for higher-octane gasoline and the regulations limiting the amount of aromatics in the fuel motivate the interest in catalytic isomerization of n-alkanes. In the last ten years, transition metal oxides or oxycarbides based on molybdenum or tungstate have attracted much attention due to their high activity and isomerization selectivity compared to the conventional bifunctional supported platinum catalyst and high resistance to sulphur and nitrogen catalyst poisons1-5. Ma… 相似文献
90.
Deposition of Hydrogen-Free Silicon Nitride Thin Films by Microwave ECR plasma Enhanced Magnetron Sputtering at Room Temperature 下载免费PDF全文
Hydrogen-free silicon nitride (SiNx) films were deposited at room temperature by microwave electron cyclotron resonance (MW-ECR) plasma enhanced unbalance magnetron sputtering system. Both Fourier-transform infrared spectroscopy and x-ray photoelectron spectroscopy are used to study the bonding type and the change of bonding structures of the silicon nitride films. The results indicate that the chemical structure and composition of SiNx films deposited by this technique depend strongly on the N2 flow rates, the stoichiometric SiNx film, which has the highest hardness of 22.9 GPa, could be obtained at lower N2 flow rate of 4 sccm. 相似文献